Dr Ir DONALD SIAHAAN
Peneliti Utama Pengolahan Hasil & Mutu
Indonesian Oil Palm Research Insitute (IOPRI)
Jl. Brigjen Katamso 51, Medan - 20158
Telp. : 061 – 7862477 ext 109, 0816407994 Since
Homepage: www.iopri.org Email: donaldjts@yahoo.com 1916
Dr Ir DONALD SIAHAAN
Peneliti Utama dan
Ketua Kelompok Peneliti Pengolahan Hasil & Mutu
Education
1999 PhD in Food Science, UPLB Los Banos
1988 Bachelor in Agricultural Technology,
Food & Nutrition Department, Bogor Agricultural
University (IPB)
Work Experience as Researcher
1989 – present : Research Officer for Postharvest
Technology in Indonesian Oil Palm Research Institute
Correspondence:
Office Mail: Jl. Brigjen Katamso 51 Medan 20158
email: donaldjts@yahoo.com, donaldjts@gmail.com
Phone: 061-7862477 ext 109
Mobile: 0812-6407-994
OUTLINE:
1. Pohon Industri & Rantai
Pasok Komoditas Kelapa Sawit
2. Produk OleoPangan
3. Produk OleoKimia
4. Produk Berbasis Biomassa
I. POHON INDUSTRI &
RANTAI PASOK
KOMODITAS KELAPA SAWIT
Lebih dari 70% produksi sawit Indonesia diekspor
ke >50 negara dalam bentuk lebih dari 150 produk
Indonesian palm oil is a global commodity for
human civilization
Thn 2011 Thn 2012 Thn 2013 Thn 2014 Thn 2015
Crude Oils (000 Ton) 12,295.4 8995.0 9,883.3 10,425.6 10,634.1
Processed Oils/Fats (000 8,277.9 14,040.0 15,273.7 15,573.4 15,971.5
Ton)
Setelah pemberlakukan PMK 128/2011 tentang bea keluar produk sawit, maka komposisi produk
ekspor berubah arah dari “raw-material “ ke “ processed product”
Saat ini, komposisi produk olahan setengah jadi dan jadi 70% terhadap 30% produk olahan dasar7
(crude oil)
MINYAK KELAPA SAWIT
Minyak Sawit Kasar POHON INDUSTRI KELAPA SAWIT Minyak Inti Sawit
(PKO)
(CPO)
(Oil Perspective)
Surfaktan Biodiesel
Confectioneries
Ester Asam Lemak : Metalic Salt : Polyethoxylated Oxygenated Fatty Fatty Alkohol Fatty Acids Amides : Gliserol Food
Fatty Amines :
Palmitat/Propand Derivates : Acid/Ester : C16&C18 Alcohol/ Emulsifier
Oleat/Ba Stearamide
Stearat Palmitat/Ethylene Secondary C16 & Sulphated
Palmitat Stearat/ Epoxy Stearic/
Propylene Oxide C18 / Ethoxylated C16&C18 Alcohol/
Metil Ester Sulfonat Ca, Zn Octanol Ester Alkanolamides
Stearat/Ethylene Epthio Stearin Esterified with
Oleat/Glycol Stearat/Ca, Mg Betain Sulphated
Propylene Oxide Mono & Higher Saturated
Propylene Glycol Fatty Acid Alcanolamide of
Stearat/ Al, Li C16 & C18 / Polyhydric Alcohol Palmitat, Stearic &
Oleic Acid Dimer C16&C19 Alcohol/
Ethoxylated Ester Oleic Acids
Oleat/ Zn, Pb Ethylene Ethoxylation
Propylene Oxide
Monogliserida Oleamide
Ethoxylation
Keterangan Warna:
= sudah diproduksi di Indonesia = belum diproduksi di Indonesia = dalam persiapan untuk di produksi
POHON INDUSTRI KELAPA SAWIT
(Perspektif Biomasa; PPKS, 2012)
TANDAN BUAH
PELEPAH DAN BATANG SAWIT
SEGAR
PANGAN
Intermediate • Minyak goreng
Industri
products • Margarine
FRKSIONASI
RAFINASI &
• Shortening
Crude
•Olein
• Vanaspati
Industri
Palm •Stearin • CBS
Oil •RBDPO • Confectionaries
(Pabrik
Kelapa
PKS
Sawit)
•PFAD • Creamer
Palm •PMF • Filled milks
Kernel • Coating fats
Oil
NON-PANGAN
OLEOKIMIA
Produk
NON-PANGAN
CRUSHING
Industri
•Fatty acids
Industri
Industri
•Kernel
• Sabun
•Fatty alcohol
• Deterjen
•Fatty amides • Shampoo
•Fatty amines • Emulsifier
•Gliserol • Biodiesel
• Explosives
Palm • Pakan ternak
• Biomass fuel
Kernel Meal
RANTAI PASOK INDUSTRI KELAPA SAWIT KINI
Downstream Consumer
Upstream Midstream
Processing Product
Crude PO
No 6
HS 1511.10.00
Degumming,
Fraksionasi tkt 1
Bleaching & Refining
SFC (%)
40
30
20
10
0
10 20 25 30 35 40
Temperature (oC)
1. Beta-Carotene
2. Tocopherol dan Tocotrienol (Vitamin E)
Karet Epoxy
plasticizer
Kertas Octylphenol
ethoxylate
Kosmetik dietanolamida
Deinking agents
Palm Oils
Defoaming agents Others Energy
Environment
Food
Dispersants for CaCO3
Plastics Water
Scouring and bleaching agents Treatment
Pulp &
Dyeing auxiliaries
Softening agents
Antistatic agents
Shade improvers Paper
Surfaktan :
Metal
Textile Surfaktan Anionik
Concrete additives
Gypsum board additives
Srfaktan Kationik
Asphalt emulsifiers.
Surfaktan Amfoterik
Oilfield
Construction Surfaktan Nonionik
Firefighting
Agro Foam
chemicals Emulsion
Polymerization
Adjuvants
Additives for agrochemicals
Anti-caking agents Detergent Explosive
Wood preservativesv Toiletries Material
Fermentation
Cosmetics
Laundry
Fermentation
detergent Additives for
additives
chemicals Foaming agents polymerization
for toothpastes 28
Cosmetics
28
Carsurin
Carsurin
chemicals MaritimeInstitute
Maritime Institute Source : Modification of KAO Indonesia Chemicals Information
Persentase Pasar Surfaktan
Konstruksi
Plastik 5.5% Bahan peledak
0.5% Pangan 0.1% Lainnya
2.3%
Polimerisasi 6.2%
emulsi
3.4%
Kertas
1.4%
margarin
Jenis Industri Jenis oleokimia yang digunakan
Agrochemical methylamine, nonylphenol ethoxylate, lauryl alcohol ethoxylate, fatty
acid athoxylate, tridecyl alcohol ethoxylate, sodium
disulfosuccinate, sodium lignosulfonate, dodecylbenzene sulfonate
Jenis Industri Jenis oleokimia yang digunakan
Karet Epoxy plasticizer, asam stearat, polyester polyol, butylamine
Jenis Industri Jenis oleokimia yang digunakan
Kertas Ethoxylated nonyl/octylphenol phosphate ester, ethoxylated linear
alcohol phosphate ester, polyoxyethylene nonyl/octylphenol,
octylphenol ethoxylate
Jenis Industri Jenis oleokimia yang digunakan
Logam Ethoxylated nonylphenol phosphate ester, linear alcohol ethoxylate,
sodium acylamido aminopropionate
4
PRODUK BERBASIS BIOMASSA
Energy
Particle board
Energy uses
MDF portion
Incineration
39
39
Carsurin
Carsurin MaritimeInstitute
Maritime Institute
Pulp and Paper
OPEFB
CHIPPING
Chemical PULPING
Pulp
PAPER
PRODUCT SPESIFICATION
• Gramatur (g/m2) : 80 – 83.5
• Thickness (mm) : Maks. 0.10
• Strength Index (Nm/kg) : 33.6 - 35
40
• Tear Index (Nm2/kg) : 6.99 – 8.80
Collaborative research IOPRI – BBS Bandung
BioChar-Briquet
Empty Fruit Bunch
(OPEFB)
CARBONIZATION
BRIQUET
DRYING
No Composition % *)
1. Ash 6.23
2. Silica 1.10
3. Lignin 20.62
4. Extractive material 7.78
5. Holo-cellulose 66.07
- Cellulose 37.50
- Hemi-cellulose 28.43
*) dry weight
43
OPEFB Pretreatment
44
OPEFB
Chopped
Fractionation Cellulose
45
Pilot scale equipment
Product:
• Cellulose > 93%
• Black liquor: - Lignin
- Hemicellulose
46
Cellulose
47 47
Cellulose: Potential Product
Sugar • Bioethanol
• Lactic Acid
48
Cellulose to Sugar
Enzyme
(Celulase and
Celobiose)
Cellulose 2 – 8 %
Enzymatic hydrolysis 72 h, 45 oC
49
Bioethanol
Should be
increaesed !!!??
Screened
Sugar Micro-organisme
(7%) (S. Cereviceae)
Ethanol
Aseton ( 20%)
Buthanol
Ethanol Aseton
50
Lactic Acid
Lactic
Acid
Lactic acid uses:
• Acid Milk, used in sour milk product
such as yoghurt and cheese
• Anti bacterial agent
Glucose • Soap-scum removal
• Monomer for producing bioplastic
and biopolymer: polylactic acid,
polylactide 51
OH
OH
OH
OH 1,2-Propanediol OR
O O
Acrylic acid
OH Esters lactic
OH
O O
H O
Lactic acid
O O
O
Lactide
Acetaldehyde
O O
OH
O O
2,3-Pentanedione Pyruvic acid
Acetic Acid
Acetobacter
Acetic
Acid
Vinyl acetate
Acetic acid
anhydride Copper acetate
Acetic acid
Esters acetate
Sodium acetate
Monochlor acetic
acid
Bioplastic
Cellulose ester
Nitrocellulose
PolyLactic Acid
Source: www.vtt.fi/inf/pdf/tiedotteet/2009/T2522.pdf
54
Cellulose ester
Cellulose ester
• Molecular weight: 25,000
• Degree subst : 2.9
Cellulose Esterification • Water abs : 0.6%
Bioplastic Film 55
BIOPLASTIK BERBASIS
MINYAK DAN BIOMASSA SAWIT
Karakter Selulosa Ester
Derajat substitusi 1.7-2.2
Perolehan 88-92% dari alfa selulosa
Kelarutan
• Larut kloroform dan toluene
• Tidak larut Air , air panas, ester dan
larutan asam
Kekuatan tarik 35 - 51 Kg/cm2
Biaya produksi IDR 5.000.000 / kg
H2SO4/HNO3
Nitrocellulose
http://en.wikipedia.org/wiki/Nitrocellulose
Nitrocellulose uses:
a- cellulose
- Plastic Film
(purity > 90%)
- Lacquer: paint, aircraft dope
- Propellants (R&D of Defense Ministry of RI)
57
PolyLactic Acid
Lactic Acid
Glucose
Polymerization
Xylose
Galactose
Manose
58
Lignin
Typical lignin
composition
Carbon : 58 - 66 %
Sodium : 0.05 - 0.4 %
Ash : 0.3 – 1 %
H2COH
H2COH
CH2
CH2
CH3O
CH2OH
Sulphur :1–3%
HO 28 CH
OH
CH
CH
H3CO
26 H2 COH
CH
HC O
Nitrogen : 0.05 - 1 %
OCH3 CH3 27
16
Carbohydrates : 0.5-1.5 %
CH O CH OCH3
6
H3CO
H C O Carbohydrate
OH 25
H COH H2COH
OCH3
OH C CH CH2OH 15
CH2OH H3CO HC O
HC O
O CH2OH H3CO HC 14 OH O CH
H3CO OCH3
O CH 24
5 7
HC O HC
O
CH2
H3CO
13
CH2OH
H2 COH
HC O
Purity can easily be improved if
HC CH HCOH
HC
HOH2C
4
OH
OCH3
H2C
O
CH O CH
HOCH
H2COH
HC O 23
needed
HOCH 8 OCH3
3 CHO
H3CO 12 CHO
HC CH2OH O
O CH H3CO 17 CH
H2C O CH CH
CH O
OHC CH CH2OH
O CH HOCH
O H2COH 22
H3CO CH2OH 9 O CH
H3CO HC OCH3
2 10 H2COH
OH H3C O HC O
18
C O H2 COH C O
H3CO 21
O CH HC CH
HC O CH2 OCH3
CH2OH HC CH2
HO 19 CH HC O
H3CO O
H2COH H COH
1
11 59
H3CO 20
HCOH
OH OCH3
HCOH
OH
H2C O
Lignin: Potential Product
Biofuel • Powder
• Pellet
• Briquette
H2COH
CH2 CH3O
Active Carbon Carrier for slow
CH2OH
H2COH CH2
HO 28 CH
OH
6
OCH3
CH
CH
16
CH3
CH
H3CO
26
O
H2 COH
CH
CH
HC O
27
OCH3
release fertilizer
H3CO
H C O Carbohydrate
OH 25 H2COH
Dispersant
H COH OCH3
OH C CH CH2OH 15
CH2OH H3CO HC O
HC O
O CH2OH H3CO HC 14 OH O CH
H3CO
5
HC
HC
O HC
HC
7
OCH3
O
CH2
CH
O
H3CO
CH
13
CH2OH
H2 COH
HC
HCOH
24
O
• Benzene
• Binder
4 H2C CH O CH
OH O H2COH
HOH2C HOCH
OCH3 HC O 23
HOCH 8 OCH3
3 CHO
H3CO 12 CHO
HC CH2OH O
O CH H3CO 17 CH
Chemicals • Phenol
H2C O CH CH
CH O
OHC CH CH2OH
O CH HOCH
O H2COH 22
H3CO CH2OH 9 O CH
H3CO HC OCH3
2 10 H2COH
• Vanilin synthetic
OH H3CO HC O
18
C O H2 COH C O
H3CO 21
O CH HC CH
HC O CH2 OCH3
CH2OH HC CH2
HO 19 CH HC O
H3CO O
H2COH H COH
1
11
H3CO 20
HCOH
OH OCH3
HCOH
OH
H2C O
Dispersant 60
Xylan Hydrogel
Others:
• Polymer (PLA)
Galactoglucomanans
• Xylitol, Furfural
• Sugar Acid
• Emulsifier
• Chemical modification 61
The Future Oil Palm Industry
Oil for
Palm Oil Mill oleoFOOD &
oleochemical
OPEFB
Fibre Processing Pulp and
Oil Palm Plantation Cellulose
Black liquor (FIBRE)
Primary Conversion NG BioFUEL
Treatment
Conversion FINE
Chemicals
Aset yang dikelola PPKS (% dalam nilai asset Rp)
BUMN BUMN
Kementerian
Kementerian Pertanian
Kantor & Perumahan Pertanian Kebun Induk
BUMN BUMN
Kementerian Kementerian
Laboratorium
Pertanian Kebun Percobaan & Pertanian
Komersial
63