stopcock buret
Buret Gay-Lussac
Buret
shutter
Buret Mohr
with
rubber
Microburet:
) Shilov air-powered Buret; ) stopcock buret
Gelas Erlenmeyer
Volumetric flask
Jika mengisi pipet or volumetric flask, atur cairan secra tepat pada daerah
kalibrasi. The liquids top surface is curved into a meniscus, the bottom of
which should be exactly even with the glasswares calibration mark. The
meniscus should be adjusted with the calibration mark at eye level to avoid
parallax errors.
m
C
N E V
m
T m/V
CN 2
C N1 V1
V2
where:
CN2 and V2 are concentration and volume
of secondary standard solution
CN1 and V1 are concentration and volume
of primary standard solution
CN
m 1000
Em V
where:
CN and V are concentration
and volume of secondary standard
solution
m and Em are mass and
equivalent weight of primary
standard
Typical
instrumentation for
performing
an
automatic titration.
Courtesy of Fisher
Scientific.
beaker
volumetric flask
Graduated cylinders
transfer pipet;
measuring pipet
direct titration
back-titration (on residue)
substitute-titration (displacement titration)
revertive titration
Revertive titration.
A standard solution is titrated by solution of
investigated substance in reversive titration
C K V E V
m
1000 V
H
T K V V
m
V
T A
(C K V C K V )E V
m
1000V
H1
T1
H2
T2
(T) E ( A )
1000
CN HCl
CN Na B O V
2 4
VHCl
Na2 B4O7
CN _ HCl
mNa CO 1000
2
EmNa CO VHCl
2
calculate
average
C N _ NaOH
CN H C O V
2
VNaOH
H 2C2O4
Lacmus
Phenolphthalein colourless
H+
Indblue
rose
CH3
-OH; -NH2; -OCH3;
N
CH3
N
C2H5
O
O
OH
O N-O-H
O
O
O N-O-H
N-O
O
+ H+
OH
colourless
yellow
yellow
1
2
Ind0 HInd H+ + Indthe acid
the base
form
form
acid . form
pH pK lg
base. form
pH pK 1
2. Indicator
On reaction products
On titration curves
Acetic acid
=1,7410-5
10 V2
x
100%
Ck Vk
Indicators error :
Hydroxyl error
Acidic error
Bases error
pT 14
10
V2
x
100%
Ck Vk
x HA 10
xMeOH 10
100%
b 14
100%
Choice of solvents: