LABORATORIUM Laboratorium Pengujian Tanggal masuk :

BALAI RISET DAN STANDARDISASI Aneka Komoditi/Pencemaran Tanggal analisis : 07/05/19

INDUSTRI PALEMBANG tanggal selesai :
No. SPK Judul Penetapan : Suhu :23 C
Kode Contoh Analisa Warna Kelembapan : 65
Jenis Contoh Metode uji : Alat :Spekto
SNI 6989.80:2011 Halaman : 1 of 1
Verifikasi Pengujian Warna dalam Air dan Air Limbah

1. Linearitas

No Kons. Std Abs

1 0 0.0001
2 1 0.0006
3 5 0.0017
4 15 0.004
5 20 0.0055
6 25 0.0065
7 30 0.0083
slope 0.00026114
intercept 0.00023298
R2 0.99656556

Kurva Kalibrasi Warna

0.009
0.008 y = 0.0003x + 0.0002
0.007 R² = 0.9966

0.006
0.005
0.004
0.003
0.002
0.001
0
0 5 10 15 20 25 30 35

Batas keberterimaan = 0.995

R2 percobaan = 0.9966

Kesimpulan : linearitas memenuhi batas keberterimaan

2. Presisi

No Ulangan Absorbans Konsentrasi

1 1 0.0011 3.1875
2 2 0.0011 3.4808
3 3 0.0011 3.4808
4 4 0.0011 3.3635
5 5 0.0011 3.1875
6 6 0.0011 3.1875
7 7 0.0011 3.3048
Rata-rata 3.3132
SD 0.1330
CV 4.015146875
 CV Horwitz
C = 0.000003313
Log C = -5.479752347
0.5 Log C = -2.739876174
1-0.5 Log C = 3.739876174
2^(1-0.5 Log C) = 13.98667379

CV Percobaan = 4.02
2/3 CV Horwitz = 9.32
Batas keberterimaan
CV Percobaan < CV Horwitz

Kesimpulan :
Presisi metode uji memenuhi batas keberterimaan

3. Akurasi

%
No Ulangan abs Konsentrasi
Recovery
1 Spiking 10.0000
2 Contoh 3.3132
3 Adisi 1 0.0036 12.8937 95.80498
4 Adisi 2 0.0035 12.5108 91.97557
5 Adisi 3 0.0037 13.2766 99.63439
6 Adisi 4 0.0036 12.8937 95.80498
7 Adisi 5 0.0037 13.2766 99.63439
8 Adisi 6 0.0035 12.5108 91.97557
9 Adisi 7 0.0035 12.5108 91.97557
Rata-rata 95.25792

Batas keberterimaan : 85-115 %

Kesimpulan :
Akurasi memenuhi batas keberterimaan

4. Instrument Detection Limit (IDL)

No Ulangan Absorbans Konsentrasi

1 1 0.0001 -0.5087
2 2 0.0001 -0.5673
3 3 0.0001 -0.6260
4 4 0.0001 -0.5087
5 5 0.0001 -0.5087
6 6 0.0002 -0.2740
7 7 0.0002 -0.0393
Rata-rata -0.4332
SD 0.2052
IDL 0.615740088

Kesimpulan :
Instrument Detection Limit sebesar 0.6157
5. Penentuan Method Detection Limit (MDL)
spike - sampel Vol Kons.
Kons spl Kons Target % + Vol spike Vol Total
Pengulangan Sampel sampel sampel Standar
(mg/L) (mg/L) Recovery standar (mL) (mL)
(mg/L) (mL) (mg/L)
(mg/L)
1 0.0000 0.7234 96.453 0.7234
2 0.0000 0.7324 97.653 0.7324
3 0.0000 0.8407 112.093 0.8407
4 0.0000 0.750 0.7234 96.453 0.7234 100.000 0.750 0.75 100
5 0.0000 0.8407 112.093 0.8407
6 0.0000 0.6060 80.800 0.6060
7 0.0000 0.7234 96.453 0.7234
Rerata 0.7414 98.857 0.7414
Standar Deviasi (SD) 0.0807
MDL = 3.143xSD 0.2537
LoQ = 10xSD 0.8073
Signal/noise (S/N) 9.1837
% RSD 10.8889
Batas Keberterimaan :
1) 10% Spike < MDL < Spike 0.08 < 0.2537 < 0.8 Diterima
2) Signal/noise (S/N): 2.5 < S/N < 10 9.1837 Diterima
3) %RSD ≤ 20% 10.8889 Diterima
4) %R = 100% ± 20% 98.8571 Diterima
5) %RSD < 2/3 Horwitz 10.8889 < 31.7173 Diterima
6) Repetability: %RSD < 1/2 Horwitz 10.8889 < 23.6696 Diterima
7) Reproducibility: %RSD < 2/3 Horwitz 10.8889 < 31.7173 Diterima
KESIMPULAN MDL 0.25 mg/L
KESIMPULAN LoQ 0.8 mg/L