Mr C6H5NH2 : 93 g/ mol

Mr asetat anhidrida : 102.9 g/mol

C6H5NH2 : 1.024 g/ mL
asetat anhidrida : 1.08 g/mL
V anilin (C6H5NH2) : 20 mL
V asam asetat glasial (CH3COOH) : 20 mL
V asetat anhidrida : 20 mL
Mr CH3COOH : 60 g/mol
Perhitungan mol asetat anhidrat
vx
Mr =

Mol asetat anhidrat=

4 mL X 1,08 g/mL
= 0,042 mL
102,09 g / mol

Perhitungan mol anilin

vx
Mr =

Mol anilin =

4 mL X 1,024 g /mL
= 0,044 mL
93 g/mol

Perhitungan mol asam asetat glasial

vx
Mr =

Mol anilin =
Anilin

4 m L X 1,051 g /mL
= 0,070 mL
60 g/mol

+ anhidrida asetat

C6H5NH2(aq

C4H6O3(aq)

asetanilida
C6H5NH(COCH3)

asam asetat
CH3COOH

0,044 mol

0,042 mol

0,042 mol

0,042 mol

0,042 mol

0,042 mol

0,002 mol

0 mol

0,042 mol

0,042 mol

Mr asetanilida

= 135,17 g/mol

Asetanilida
0,042 mol =

m
Mr
m
135,17 g /mol

m = 5,68 g
massa asetanilida keseluruhan

= 5,68 g

massa asetanilida rekristalisasi 1 g

= 0,38 g

8,64 g x gram

1 gram 0,38 gram

8,64 gram
1 gram
x gram

x gram
0,38 gram

= 3,28 gram

Rendemen =

3,28 g
5,68 g

x 100%

= 57,75 %
Mekanisme Reaksi
Pembentukan ion nitronium :
O
H

+ H

H
O

O
O

HSO4

H2O

Nitrasi Asetanilida
O

O
HN

NH C

O
CH3

HN

CH3

CH3
+

NO2
O
NH C
CH3

H2SO4

NO2

H
NO2

HSO4-