Kelompok 2

K I M O R
ALKANA JENUH DAN ALKIL

Disusun Oleh :

 Cicik Ari Kusuma

 Dhimas Praditya Rezky
 Eva Nur Haliza
 Salma Nur Syahidah

Kimia Organik
 KLASIFIKASI SENYAWA HIDROKARBON
senyawa yang tersusun dari atom unsur
karbon (C) dan hidrogen (H)

1. Hidrokarbon Alifatik
Hidrokarbon dengan rantai terbuka dengan
ikatan tunggal (jenuh) ataupun ikatan rangkap
(tak jenuh).

3. Hidrokarbon Aromatik
hidrokarbon rantai melingkar dengan ikatan
konjugasi, yaitu ikatan tunggal dan ikatan
rangkap yang berselang-seling.

2. Hidrokrbon Alisiklik
hidrokarbon dengan rantai tertutup atau
melingkar.
ALKANA
 Definisi

Alkana
Alkana adalah senyawa hidrokarbon alifatik
jenuh. Alkana membentuk deret homolog,
yaitu kelompok senyawa dengan rumus
umum sama dan sifat bermiripan.

Berikut tabel deret homolog alkana dengan rumus molekul,

rumus umum :
rumus bangun, dan nama dari masing-masing senyawa.
CnH2n+2
 Sifat – Sifat Senyawa Alkana
1.    Pada suhu kamar C1–C4 berwujud
gas, C5–C17 berwujud cair, dan di atas 17
berwujud padat
2. Semakin bertambah jumlah atom C maka Mr ikut
bertambah akibatnya titik didih dan titik leleh semakin
tinggi. Alkana rantai lurus mempunyai titik didih lebih
tinggi dibanding alkana rantai bercabang dengan jumlah
atom C sama. Semakin banyak cabang, titik didih makin
rendah.
3. Alkana mudah larut dalam pelarut
organik tetapi sukar larut dalam air.
4. Pembakaran/oksidasi alkana bersifat eksotermik
(menghasilkan kalor). Pembakaran alkana
berlangsung sempurna dan tidak sempurna.
Pembakaran sempurna menghasilkan gas
CO2 sedang pembakaran tidak sempurna
menghasilkan gas
5. Alkana dapat bereaksi substitusi dengan
halogen. Reaksi substitusi adalah reaksi
penggantian atom/ gugus atom dengan
atom/gugus atom yang lain.
6.    Senyawa alkana rantai panjang dapat mengalami
reaksi eliminasi. Reaksi eliminasi adalah reaksi
penghilangan atom/gugus atom untuk memperoleh
senyawa karbon lebih sederhana.
Contoh pada reaksi eliminasi termal minyak bumi dan
gas alam.
 Tata Nama Senyawa Alkana
1
Rantai C yang terpanjang ditetapkan
sebagai rantai utama. Bila terdapat dua
atau lebih rantai terpanjang yang sama
panjangnya, maka dipilih rantai dengan
cabang terbanyak sebagai rantai utama
3 Untuk substituen cabang yang sejenis
Atom-atom C pada rantai utama
diberi nomor secara berurut dimulai
dari salah satu ujung rantai yang
posisi cabangnya mendapat nomor
terkecil
Aturan IUPAC untuk penamaan alkana
2
Cabang dari rantai utama dengan
substituen hidrokarbon (gugus alkil) 5
diberi nama dengan mengganti
akhiran ana pada alkana menjadi il.
Berikut tabel struktur dan nama dari Substituen-substituen cabang ditulis
beberapa gugus alkil. berdasarkan urutan alfabetik. Awalan
substituen seperti di, tri, n–
(normal), sek– (sekunder), ters–
(tersier) diabaikan dalam pengurutan
alfabetik kecuali awalan iso tidak
diabaikan
4
dinyatakan dengan awalan di,
tri, tetra, penta,
Contoh nama - nama senyawa alkana
 Isomer
Isomer ialah molekul-molekul dengan rumus Isomer Rangka
kimia yang sama (dan sering dengan
jenis ikatan yang sama), tetapi memiliki susunan
yang berbeda. Isomer dibagi menjadi 2 jenis
yaitu struktur dan ruang

Pada alkana, senyawa jenuh ini hanya memiliki

2 jenis isomer yaitu isomer struktur, lebih
tepatnya isomer rangka dan posisi.

Isomer Rangka → rumus molekul sama,

rumus/rangka berbeda Isomer Posisi

Isomer Posisi → rumus molekul sama, tetapi

gugus/cabang berbeda
 Kegunaan Alkana

Metana Propana Oktana

Berguna sebagai bahan
merupakan komponen
bakar untuk memasak, merupakan komponen
utama gas elpiji untuk
dan bahan baku utama bahan bakar
memasak dan bahan
pembuatan zat kimia kendaraan bermotor,
baku senyawa organik.
seperti H2 dan NH3 yaitu bensin

berguna sebagai bahan

bakar untuk memasak berguna sebagai bahan
dan sebagai refrigerant bakar kendaraan dan
dalam sistem bahan baku karet
pendinginan dua tahap sintesis.
untuk suhu rendah.

Etana Butana
 ALKIL

Alkil adalah radikal univalen yang hanya
mengandung atom karbon dan hidrogen yang
disusun dalam satu rantai. Alkil membentuk
rangkaian yang dapat disederhanakan dalam
rumus CnH2n+1. Misalnya, metil, CH3· (diturunkan
dari metana) dan butil C4H9· (diturunkan
dari butana).
 Contoh

1
Struktur 3-metil pentana terdiri atas dua bagian. Yang pertama, rantai lurus
terpanjang yang tediri dari 5 atom karbon, yang disebut pentana (diwarnai
dengan warna biru).

2 Gugus alkil, dengan panjang 1 karbon, disebut metil (warna merah).

3 Alkil tersebut terdapat pada atom ketiga dari rabtai pentana, maka itu
disebut 3-metil pentana.

4 Jika terdapat lebih dari satu gugus alkil yang berikatan pada rantai, amak
digunakan awalan (seperti di, tri, tetra, dan lainnya).
Reaksi Pada Alkana

01 Oksidasi

02 Halogenasi

03 Nitrasi

04 Sulfonasi
 Reaksi Pada Alkana
Add Text Add Text
OKSIDASI HALOGENASI
Alkana bila berekasi dengan Alkana bereaksi dengan
oksigen dalam jumlah yang
memadai (teroksidasi sempurna)
membentuk CO2 dan H2O
A B halogen di bawah pengaruh
panas atau sinar ultraviolet.
Contoh:
disertai pembebasan panas.
Contoh : CH4 + Cl2  CH3Cl + HCl

Pada contoh reaksi di atas

CH4 + 2 O2  CO2 + 2H2O + panas terjadi penggantian satu atom
H pada metana oleh atom
halogen. Reaksi ini termasuk
reaksi substitusi dan karena
substitusinya haogen, maka
disebut halogen.
 Reaksi Pada Alkana
NITRASI
Reaksi alkana dengan HNO3 pada suhu
150-475° C mengakibatkan terjadinya
substitusi atom H pada alkana oleh gugus
–NO2 (gugus nitro). Reaksi substitusi
semacam ini dinamakan reaksi nitrasi dan
secara umum dituliskan dengan
persamaan reaksi :
R-H + HO-NO2  R-NO2 + H2O
Seperti halnya halogenasi, atom-atom
dalam alkana berbeda laju reaksinya
dalam nitrasi sehingga hasil nitrasi
cenderung membentuk campuran. Contoh
:
CH3CH2CH3 + HNO3  CH3CH2CH2NO2 + CH3CH(NO2)CH3
Add Text Add Text
SULFONASI
Reaksi alkana dengan asam sulfat
A B pekat berasap (oleum) menghasilkan
asam alkana sulfonat dan dituliskan
dengan persamaan reaksi umum :
R-H + HO-SO3H-  RSO3H + H2O
Dalam reaksi di atas terjadi substitusi
satu atom H pada alkana oleh gugus –
SO3H dan substitusi ini dinamakan
sulfonasi. Dalam reaksi sulfonasi
terbukti bahwa lau substitusi
H3 > H2 > H1
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Place Your Picture Here Place Your Picture Here Place Your Picture Here Place Your Picture Here Place Your Picture Here

Contents Here Contents Here Contents Here Contents Here Contents Here
You can simply impress You can simply impress You can simply impress You can simply impress You can simply impress
your audience and add your audience and add your audience and add your audience and add your audience and add
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01 You can simply impress your audience and add a unique 02 You can simply impress your audience and add a unique
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 One Columns Text
PowerPoint Presentation

You can simply impress your audience and add a unique zing and appeal to
your Presentations. I hope and I believe that this Template will your Time,
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You can simply impress your audience and add a unique zing and appeal to
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Two Columns Text
01 PowerPoint Presentation

You can simply impress your audience and add a unique zing
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this Template will your Time, Money and Reputation. You can
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PowerPoint Presentation

Thank You
Insert the Sub Title of Your Presentation
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Science Technology Engineering Arts Mathematics
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 Fully Editable Icon Sets: B

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