EKSPERIMEN TITRASI BERBASIS KOMPUTER

Heli Siti Halimatul M., Siti Aisyah, Galuh Yuliani

(Kamis, 20 Mei-4 Juni 2020)

A. Tujuan Eksperimen
1. Terampil merancang percobaan melalui pengamatan program Screen titration experiment
2. Terampil menganalisis tahapan-tahapan proses titrasi melalui pengamatan program Screen
titration experiment.
3. Terampil melakukan ekperimen titrasi secara virtual.

B. Kegiatan aktivitas online

a. Petunjuk Pengoperasian Simulator
1. Klik tautan di bawah untuk melakukan eksperimen titrasi secara virtual.
http://www.rsc.org/learn-chemistry/resources/screen-experiment/titration/experiment/2

2. Klik Register untuk merekam seluruh aktifitas saudara dalam ekperimen yang akan dilakukan
dan untuk memperoleh nomor registrasi untuk login kembali pada menu yang telah
dikerjakan. Gunakan nama lengkap dan NIM pada saat registrasi. Contoh: Heli190520.
3. Setelah login, Klik menu “titration home” dan pilih sub menu “Quickstart”.
4. Lakukan secara bertahap setiap level titrasi dan kerjakan secara penuh seluruh aktifitas dalam
setiap tahapan titrasi. Pahami setiap tayangan video yang ditampilkan pada setiap tahapan
titrasi untuk melengkapi secara penuh seluruh kegiatan pada setiap tahapan. Setiap aktifitas
akan direkam dalam lab log book. Pastikan Saudara mengerjakan secara tuntas terlebih
dahulu seluruh aktifitas hingga akhir baru print lab log book. Catatan: Laporkan hasil kegiatan
pertama dan bukan hasil restart program.
5. Unduh lab book untuk dilaporkan setelah saudara selesai melakukan keseluruhan ekperimen
titrasi untuk seluruh level.

SELAMAT BEREKSPERIMEN SECARA VIRTUAL DI RUMAH

Stay safe and keep health
LAPORAN KEGIATAN TITRASI VIRTUAL
NAMA : Kanthi Pawening
Tyas
NIM : 1906272
ID LOGIN : 7592481170
SKOR TITRASI (POIN)
PENGULANGAN
TITRASI TITRASI TITRASI TITRASI TOTAL
(RESTART)
LEVEL I LEVEL II LEVEL III LEVEL IV AKHIR
0 980 750
1 1000
2
3
DST

*Berikan laporan secara jujur jika Saudara melakukan restrart pada setiap level titrasi
yang dilakukan.

LAMPIRAN
(PDF LAB BOOK)


Titration level 1
Aims
In level 1, you'll analyse samples from a river that has been contaminated with acid. You'll perform titration
experiments to work out the concentration of acid in the samples.

In each activity you'll be able to collect points. At the end of the level you can restart to improve your skills.

Video 100 Points

Comprehension 100 Points 1 Attempt

Hydrochloric acid fully dissociates when dissolved in water.

The pH of water is approximately 7 which means it is neutral.

When an acid and alkali react to form water and salt it is called neutralisation.

A titration experiment can be used to determine the unknown concentration of acid using a known concentration of
base.

An indicator helps us to see the point of neutralisation during a titration experiment by causing a colour change.

Acids and alkalis 100 Points

pH 0-2 pH 7 pH 12-14

hydrochloric acid distilled water sodium hydroxide

sulfuric acid potassium hydroxide

nitric acid calcium hydroxide

Phenolphthalein is an indicator which changes colour close to the point of neutralisation and is used to show the end-
point of this titration. When adding a strong acid to a strong base the phenolphthalein indicator changes colour from
pink to colourless.

Weighing 100 Points 1 Attempt

You correctly used the balance to accurately weigh:

Mass of sodium hydroxide = 1.01 g

This was transferred to a beaker for you ready for the next step of the experiment.

Standard solution 100 Points

First the sodium hydroxide powder was dissolved in distilled water.
Next you transferred to solution to a 250.0 cm3 volumetric flask and rinsed the beaker with more water.

Finally you made up the standard solution to the to the 250.0 cm3 level using a dropping pipette

Alkali concentration 100 Points

You calculated the molar mass for sodium hydroxide as 40 g mol-1.

Then you worked out the amount of sodium hydroxide you used was0.0253 mol.

Finally you calculated the concentration of your stock solution as being 0.10 mol dm-3.

Preparing for titration 90 Points 1 Attempt

First you rinsed a pipette with your sodium hydroxide solution.

Next you used the pipette to transfer exactly 25.00 3 of the solution into a conical flask and added 2 drops of
phenolphthalein indicator.

Burette setup 90 Points 1 Attempt

First you rinsed a burette with distilled water.

Next you rinsed the burette with your acidic contaminated river sample.

Then you filled the burette with the river sample and ensured the eye level was good for reading the burette level

Then you removed the funnel.

Finally the burette was filled below the tap by running out some solution.

Titration experiment 100 Points

You performed titration experiments on contaminated river water from two sites B and C.

1st 2nd
Sample site
Trial accurate accurate
B
titration titration

Final reading
26.80 28.60 27.20
(cm3)

Initial reading
8.65 11.30 9.90
(cm3)

Volume added
18.15 17.30 17.30
(cm3)

Average
volume added 17.30
(cm3)

Sample site 1st 2nd

Trial accurate accurate
C
titration titration

Final reading
44.70 47.05 44.40
(cm3)

Initial reading
8.90 11.75 9.10
(cm3)

Volume added
35.80 35.30 35.30
(cm3)

Average
volume added 35.30
(cm3)

Number of times
that sample B 1
was tested

Average volume
added for all 17.30
samples (cm3)

Number of times
that sample C 1
was tested

Average volume
added for all 35.30
samples (cm3)

Titration analysis 100 Points

You correctly determined the concentration of acid in the river at sites B and C.

Amount of sodium hydroxide = 0.0025 mol.

Amount of hydrochloric acid = 0.0025 mol.

Concentration of hydrochloric acid at site B = 0.14 mol dm-3.

Concentration of hydrochloric acid at site C = 0.07 mol dm-3.

The pH of the river is normally neutral.

The pH values increase as the concentration of HCl decreases.

The pH at the site of special scientific interest is bad.

The pH of the river returns to a moderate level by the time it reaches site D.

Review
You have not completed this section yet.


Titration level 1
KanthiPaweningTyas1906272

Aims
You have not completed this section yet.

Video 100 Points

Comprehension 100 Points 1 Attempt

Hydrochloric acid fully dissociates when dissolved in water.

The pH of water is approximately 7 which means it is neutral.

When an acid and alkali react to form water and salt it is called neutralisation.

A titration experiment can be used to determine the unknown concentration of acid using a known concentration of
base.

An indicator helps us to see the point of neutralisation during a titration experiment by causing a colour change.

Acids and alkalis 100 Points

pH 0-2 pH 7 pH 12-14

hydrochloric acid distilled water sodium hydroxide

sulfuric acid potassium hydroxide

nitric acid calcium hydroxide

Phenolphthalein is an indicator which changes colour close to the point of neutralisation and is used to show the end-
point of this titration. When adding a strong acid to a strong base the phenolphthalein indicator changes colour from
pink to colourless.

Weighing 100 Points

You correctly used the balance to accurately weigh:

Mass of sodium hydroxide = 1.00 g

This was transferred to a beaker for you ready for the next step of the experiment.

Standard solution 100 Points

First the sodium hydroxide powder was dissolved in distilled water.

Next you transferred to solution to a 250.0 cm3 volumetric flask and rinsed the beaker with more water.
Finally you made up the standard solution to the to the 250.0 cm3 level using a dropping pipette

Alkali concentration 100 Points

You calculated the molar mass for sodium hydroxide as 40 g mol-1.

Then you worked out the amount of sodium hydroxide you used was0.0250 mol.

Finally you calculated the concentration of your stock solution as being 0.10 mol dm-3.

Preparing for titration 100 Points 1 Attempt

First you rinsed a pipette with your sodium hydroxide solution.

Next you used the pipette to transfer exactly 25.00 3 of the solution into a conical flask and added 2 drops of
phenolphthalein indicator.

Burette setup 100 Points 1 Attempt

First you rinsed a burette with distilled water.

Next you rinsed the burette with your acidic contaminated river sample.

Then you filled the burette with the river sample and ensured the eye level was good for reading the burette level

Then you removed the funnel.

Finally the burette was filled below the tap by running out some solution.

Titration experiment 100 Points

You performed titration experiments on contaminated river water from two sites B and C.
 1st 2nd
Sample site
Trial accurate accurate
B
titration titration

Final reading
26.60 25.15 26.00
(cm3)

Initial reading
10.20 8.60 9.45
(cm3)

Volume added
16.40 16.55 16.55
(cm3)

Average
volume added 16.55
(cm3)

1st 2nd
Sample site
Trial accurate accurate
C
titration titration

Final reading
44.00 46.35 45.25
(cm3)

Initial reading
9.40 11.70 10.60
(cm3)

Volume added
34.60 34.65 34.65
(cm3)

Average
volume added 34.65
(cm3)

Number of times
that sample B 1
was tested

Average volume
added for all 16.55
samples (cm3)

Number of times
that sample C 1
was tested

Average volume
added for all 34.65
samples (cm3)

Titration analysis 100 Points

You correctly determined the concentration of acid in the river at sites B and C.

Amount of sodium hydroxide = 0.0025 mol.

Amount of hydrochloric acid = 0.0025 mol.

Concentration of hydrochloric acid at site B = 0.15 mol dm-3.

Concentration of hydrochloric acid at site C = 0.07 mol dm-3.

The pH of the river is normally neutral.

The pH values increase as the concentration of HCl decreases.

The pH at the site of special scientific interest is bad.

The pH of the river returns to a moderate level by the time it reaches site D.

Review
You have not completed this section yet.


Titration level 2
KanthiPaweningTyas1906272

Aims
You have not completed this section yet.

Video 100 Points

Comprehension 90 Points 2 Attempts

Aspirin contains a carboxylic acid group and is a weak acid.

Aspirin molecules partially dissociate in water.

The hydroxide ion of the strong base reacts with the conjugate base of the aspirin molecule.

The end-point of a titration experiment occurs when there is a sudden change in pH.

A suitable indicator compound will change colour near the end-point of the titration.

Aspirin preparation 70 Points 3 Attempts

First the tablets were ground into a fine powder with a pestle and mortar.

Next you added water to dissolve the aspirin.

Finally you made the solution up to 250.0 cm3 using a volumetric flask.

Preparing for titration 100 Points 1 Attempt

First you rinsed a pipette with aspirin solution.

Next you used the pipette to transfer exactly 25.00 cm3 of the solution into a beaker.
Burette setup 90 Points 1 Attempt
First you rinsed a burette with distilled water.

Next you rinsed the burette with sodium hydroxide solution.

Then you filled the burette with sodium hydroxide solution.

Then you removed the funnel.

Finally the burette was filled below the tap by running out some solution.

pH meter 100 Points

First you used the pH probe to obtain a plot of pH against volume added from the burette. From the data, you selected
phenolphthalein and bromothymol blue as suitable indicators for the titration experiment.

Titration experiment 100 Points

1st 2nd 3rd

Trial accurate accurate accurate
titration titration titration

Final reading
29.85 30.35 30.90 28.20
(cm3)

Initial reading
10.55 11.45 11.75 9.05
(cm3)

Titre (cm3) 19.30 18.90 19.15 19.15

Mean titre
19.15
(cm3)

The results of the trial and 1st accurate titration were excluded from the average volume calculation.

Mean titre: 19.15 cm3.

Titration analysis 100 Points
Concentration of NaOH solution = 0.1 mol dm-3.

Mean titre (NaOH solution) = 19.15 cm3.

Amount of NaOH = 0.00191 moles.

Molar ratio of NaOH:aspirin = 1:1.

Amount of aspirin = 0.00191 moles.

Mass of aspirin (in titration) = 0.344 g.

Mass of aspirin (per tablet) = 0.344 g.

You correctly determined the amount of 2-ethanoyloxybenzene carboxylic acid in each tablet and compared this with
quality standards.

Review
Things I did well on:

Things I could improve on:

From your titration experiment, what are the potential errors which could lead to inaccurate results?