BESI (IRON)
Elemen Pencampur (Alloying
element)
CARBON
0.2 – 2.08%
by weight
HARDENING AGENTS ALLOY BAJA
Other alloying elements (STEEL)
Mencegah dislokasi dalam
kisi kristal atom besi • Manganese
• Chromium
Variasi Jumlah Variasi Bentuk • Molybdenum
• Vanadium
• Nickel
Kontrol Kualitas/Control Quality • Cu
• etc
• Kekerasan/Hardness
• Keuletan/Ductility
• Kuat Tarik/Tensile Strength Fe 1538oC
Highest metal melting point W: 3,422oC
Ref.2 Highest Element Melting point: C: 3,527oC sublimate
Dislokasi
Dislokasi adalah cacat
satu dimensi sekitar
yang beberapa atom
tidak sejajar.
Merupakan cacat
kristalografi atau
ketidakteraturan
dalam struktur kristal
Kehadiran dislokasi Dislokasi ulir
sangat mempengaruhi
banyak sifat material.
Dislokasi tepi
BAJA KARBON
DEFINISI METALURGIS:
BAJA (STEEL) : BESI DENGAN KADAR
KARBON < 2,1%
BESI COR (CAST IRON) : BESI DENGAN KADAR
KARBON > 2,1%
Carbon Equivalent
CE
CE = C + Mn + Ni+Cu + Cr+Mo+V %
6 15 5
Efek pada mampu las dari unsur-unsur seperti Chromium (Cr) dan Vanadium (V), tidak
sebesar Carbon (C), tapi lebih signifikan daripada tembaga (Cu) dan Nikel (Ni)
Ref.2
IRON Allotropy
Properti beberapa unsur kimia untuk dapat berupa dua atau lebih yang bentuk yang
berbeda, di mana atom-atom disusun secara berbeda oleh ikatan kimia (dalam fase yang
sama)
a-Fe alpha iron, forms < 770oC (Tc), magnetic, BCC crystal structure,
Ferrite
d-Fe delta iron, forms from cooling down molten iron < 1538oC, BCC
Carbon: Diamond (atom in tetrahedral crystal) and Graphite (atom in hexagonal lattice)
Oxygen: O, O2 and O3 in gas phase
Tc : Curie Point
TRICLINIC The 7 Crystal System
(parallelepiped)
MONOCLINIC
(right prism with parallelogram base)
ORTHOROMBIC
(cuboid)
TETRAGONAL
(square cuboid)
RHOMBOHEDRAL
(trigonal) (3-sided trapezohedron)
HEXAGONAL
(centered regular hexagon)
CUBIC
(isometric, cube)
Ref.2
Metastable Fe-C Phase Diagram Under atmospheric pressure
d Fe 1600
+ liquid 1538 oC
1500
1495 oC
d Fe Liquid
1400
d Fe+ g Fe 1394 oC
1300
TEMPERATURE oC
Fe3C + ledeburite
2.08 %
1000
912 oC
gFe +Fe3C + ledeburite
900
b Fe 0.68 %
800
770 oC a+g 738 oC
a Fe 700
Fe3C + ledeburite + pearlite
600
0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0
aFe + pearlite Pearlite (eutectoid) MASS % Carbon Ledeburite (eutectic)
Fe 0% C < Steel < 2.08% C 2.08% C < Cast Iron < 6.67% C Fe3C
Ref.2
Metastable Fe-C Phase Diagram Under atmospheric pressure
d Fe 1600
+ liquid 1538 oC
1500
1495 oC
d Fe Liquid
1400
d Fe+ g Fe 1394 oC
1300
TEMPERATURE oC
Fe3C + ledeburite
2.08 %
1000 HEAT TREATMENT
912 oC
gFe +Fe3C + ledeburite
900
b Fe 0.68 %
800
770 oC a+g 738 oC
a Fe 700
Fe3C + ledeburite + pearlite
600
0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0
aFe + pearlite Pearlite (eutectoid) MASS % Carbon Ledeburite (eutectic)
Fe 0% C < Steel < 2.08% C 2.08% C < Cast Iron < 6.67% C Fe3C
FASA PADA BAJA KARBON
FASA PADA BAJA :
FERIT = FASA α (BCC) DENGAN ATOM C YANG LARUT PADAT; SIFAT
LUNAK & ULET
AUSTENIT = FASA Y (FCC) DENGAN ATOM C YANG LARUT PADAT; FASA PADA
SUHU TINGGI; LUNAK & ULET
SEMENTIT = SENYAWA Fe3C = BESI KARBIDA; SANGAT KERAS SEKALI &
GETAS
PERLIT = FASA EUTEKTOID TERDIRI DARI FERIT + SEMENTIT YANG
BERLAPIS-LAPIS; KUAT & CUKUP ULET
Tempering adalah teknik pemanasan ulang untuk "menguatkan (toughing)" baja dengan
mengubah martensit yang brittle/getas menjadi bainit atau kombinasi dari ferit dan
sementit
Pertama dipanaskan untuk membuat larutan padat dari besi dan karbon dalam proses
yang disebut austenizing. Austenisasi ini diikuti dengan quenching (pendinginan) untuk
menghasilkan mikrostruktur martensit.
Baja tersebut kemudian dilakukan tempering dengan pemanasan antara rentang 150 ° C-
260 ° C (300 ° F-500 ° F) dan 370 ° C-650 ° C (700 ° F-1200 ° F). Tempering di kisaran 260 °
C-370 ° C (500 ° F-700 ° F) seringkali dihindari untuk mengurangi getas temperring.
Baja ini dijaga pada suhu tersebut sampai karbon yang terperangkap dalam martensit
berdifusi untuk menghasilkan komposisi kimia dengan potensi untuk menghasilkan baik
bainit atau perlit (struktur kristal yang terbentuk dari campuran ferit dan sementit).
Ref.2
ANNEALING
Baja dipanaskan sekitar 25oC diatas suhu kritis atas, ditahan selama
waktu yang ditetapkan dan kemudian didinginkan perlahan-lahan dalam
tanur (furnace). Proses ini digunakan untuk menghilangkan tegangan
internal yang dihasilkan sebagai akibat dari proses pekerjaan
pendinginan dan fabrikasi.
Full anneal: Bila bagian yang di-annealing dibiarkan dingin dalam furnace.
Normalizing: Bila bagian yang di-annealing dikeluarkan dari furnace dan dibiarkan
dingin di udara
Ref.2
QUENCHING
• Air suling biasa (soft distilled water) adalah media yang lebih disukai bila menggunakan air untuk
pendinginan baja karbon.
• Air seharusnya tidak memiliki kotoran seperti minyak, lemak atau asam karena bisa mengakibatkan
pengerasan yang tidak merata jika menempel pada permukaan baja yang keras yang memberikan isolasi
termal lokal.
• Air keras tidak memuaskan karena dapat menghasilkan kerak saat suhu dinaikkan. Sabun kadang-
kadang ditambahkan untuk mengatur tingkat pendinginan. Air garam dingin atau air digunakan untuk
menyediakan pendinginan (quenching) yang paling ekstrim dengan hasil kekerasan maksimum.
Perawatan yang hati-hati dibutuhkan dalam pemilihan penampang yang dikeraskan sebagai hasil proses
“thermal shock” dengan konsekuensi crack dan distorsi.
• Quenching dengan minyak digunakan di mana kekerasan yang ekstrim tidak diperlukan dan di perlukan
fleksibilitas “quenching shock”. Minyak yang digunakan adalah terutama minyak mineral dengan
viskositas dipilih sesuai dengan jenis baja yang akan di-quenching. Sistem pendingin minyak diperlukan
saat kapasitas pendinginan yang signifikan diperlukan untuk mencegah minyak dari tidak berfungsi dan
untuk menjaga kondisi quenching. Pendingin udara digunakan untuk proses pengerasan ringan bila
struktur perlitik yang keras dan tangguh diperlukan.
Ref.2
Ref.2
Crystal Structure Fe
Carbon
Pengerasan melibatkan pemanasan baja sampai suhu
normalisasi dan pendinginan (Quenching) dengan cepat dalam
cairan yang sesuai. misalnya minyak, air atau udara
g-Fe
a-Fe TEMPERING
When steel is heated above the upper critical temperature (about 760oC), the iron crystal
structure will change from BCC to FCC, and the carbon atoms will migrate into the central
position formerly occupied by an iron atom. This form of red-hot steel is called austenite (γ iron).
Ref.2
Crystal Structure Fe
Carbon
g-Fe Pearlite
ANNEALING
If this steel form cools slowly, the iron atoms move back into the cube forcing the carbon atoms
back out, resulting in soft steel called pearlite. If the sample was formerly hard, this softening
process is called annealing.
Ref.2
Crystal Structure Fe
Carbon
Martensite
g-Fe
QUENCHING
FACE-CENTERED CUBIC
BODY-CENTERED TETRAGONAL
If the steel is cooled quickly (quench) by immersing it in oil or water, the carbon atoms are
trapped, and the result is a very hard, brittle steel. This steel crystal structure is now a body
centered tetragonal (BCT) form called martensite.
Ref.2
IRON Alloy Phases
AUSTENITE
FCC (face-centered-cubic)
QUENCHING
Rapid cooling of austenite which traps carbon atoms that do not have time to diffuse out
of the crystal structure, becomes martensite
MARTENSITE
BCT (body-centered-tetragonal)
Hardest and most brittle type of steel
TEMPERING
is a heat treatment technique to "toughen" the metal by transforming brittle martensite
into bainite
BAINITE
Ref.2
combination of ferrite and cementite
Steel Groups and Class as per API RP2A
• GROUP 1 • CLASS A
• GROUP 2 • CLASS B
• GROUP 3 • CLASS C
Ref.2
Steel Groups and Class as per API RP2A
STEEL GROUPS
(Based on Strength Level and Welding characteristics)
Group 1
Mild Steel, Fy < 280 MPa (40 ksi) , CE < 0.40%. Welding process AWS
D1.1
Group 2
Intermediate Strength Steel, 280 MPa (40 ksi) < Fy < 360 MPa (52 ksi) ,
CE > 0.45%.
Low Hydrogen Welding process
Group 3
High Strength Steel Fy > 360 Mpa (52 ksi). Have to check the weldability,
Fatigue problems and Notch Toughness prior to utilization
Ref.2
Steel Groups and Class as per API RP2A
STEEL CLASSES
(Based on Notch Toughness characteristics and service temperature)
Class C
Temperature above 0oC, impact tests are not specified, limited thickness,
moderate forming, modest stress
Class B
Temperature 10oC to 0oC, Charpy V-notch energy 20J (Group 1) and 34J
(Group 2)
Class A
Suitable for subfreezing temperature.
Temperature -20oC to -40oC, Charpy V-notch energy 20J (Group 1) and 34J
(Group 2)
Ref.2
API RP2A
A36 I C 36 58 – 80 <2
A131 Grade A I C 34 58 – 80 < 0.5
A709 Grade 36T2 I B 36 58 – 80
A572 Grade 42 II C 42 60 <2
A572 Grade 50 II C 50 65 <2
A709 Grades 50T2, 50T3 II B 50 65
A131 Grade AH32 II B 45.5 68 – 85
A131 Grade AH36 II B 51 71 – 90
Ref.2
API RP2A
Ref.2
ASTM American Society for Testing and Materials
“A” is alloy identification and then followed by two, three, or four numbers.
The Yield Strength, the stress that can be applied to a base metal or weld without
permanent deformation of the metal.
The Tensile Strength, "the ultimate tensile strength" is the maximum tensile
strength that the metal or weld can with stand before failure occurs
The preheat temperatures provided are when low hydrogen electrodes used.
Consider all the TIG and gas shielded flux cored electrodes as low hydrogen
consumables.
Ref.2
Steel Properties
When a material has reached the limit of its strength, it usually has the option of
either deformation or fracture.
Ref.2
Ductility
Examples of highly ductile metals are silver, gold, copper, and aluminum. The
ductility of steel varies depending on the alloying constituents. Increasing levels
of carbon decreases ductility, i.e., the steel becomes more brittle.
Ref.2
Brittleness
That is, it has little tendency to deform (or strain) before fracture
This fracture absorbs relatively little energy, even in materials of high strength,
and usually makes a snapping sound
Preheat, inter-pass temp controls and post heat all are designed to reduce the
potential for brittleness
Ref.2
Metallic Bonding
When seen as the sharing of 'free' electrons among a lattice of positively-charged metal
ions.
In a more quantum mechanical view the conduction electrons divide their density equally
over all atoms that function as neutral (non-charged) entities.
In metallic bonding, bonding electrons are delocalized over a lattice of atoms. Because of
delocalization or the free moving of electrons, it leads to the metallic properties such as
strength, malleability, ductility, conductivity of heat and electricity, ductility and hardness.
Chemical bonds
Strong:
Covalent Bonds
Metallic Bond
Ionic Bond
Weak:
Hydrogen Bond
Non covalent Bonds
van der Waals
Ref.2
Toughness
It is defined as the amount of energy per volume that a material can absorb before rupturing
Toughness tests:
• Charpy Impact Test
• Izod Impact Test
Unit of Toughness:
Toughness is measured in units of Joules per cubic meter (J/m3) or (in·lbf/in3)
Ref.2
Charpy Impact Testing Equipment
Ref.2
Charpy Impact Test machine
scale
hammer
pointer
anvil 10 mm
Hammer
A’
specimen
anvil
Ref.2
Base Metal: Weldability
The disadvantage to using plain carbon and low-alloy steels is their lower
strength—there is a trade-off between material strength and weldability.
Ref.2
Iron and Steel
Ref.2
Stainless Steel
When enough chromium (more than about 10%) is added to ordinary steel, the
oxide on the surface is transformed - it is very thin, virtually invisible and
protective in a wide range of corrosive media.
Ref.2
Stainless Steel
Ferritic stainless steel, are magnetic, not as easily welded, and must often be
preheated and welded with special electrodes.
Martensitic stainless steels, are magnetic, not as easily welded, and must often
be preheated and welded with special electrodes.
Austenitic grades of stainless steels is non magnetic and tend to be the most
weldable stainless steel.
Ref.2
Stainless Steel
Ferritic Stainless Steel
• Basic: Fe C Cr
• Crystal Structure: Ferrite
• Magnetic (Ferromagnetic)
• Least Expensive
• Difficult to form and weld
• Type 430
Ref.2
Stainless Steel
Martensitic Stainless Steel
Add Nickel
Ref.2
TEMPERING
COLOR TEMPERATURE OC
Ref.2
JACKET STRUCTURE FABRICATION
ASTM A-36, ASTM A572 Gr 50 (ROLLED PLATE to API Spec 2B)
API 5L Grade B (STEEL PIPE)
API Spec 2H for joint cans
(ROLLED STEEL PLATE to API Spec 2B)
Tubular members
Spiral welded pipes can not be used as per API RP2A
Tubulars D/t, local buckling BRACING
KL/r values, slenderness ratio
ANODES
Welding
AWS D1.1 Section 10 for tubular structures
AWS D1.1 Section 8 for plates and structural shapes
Ref.2
Tubular Welded Joint
Joint Weld
Longitudinal
Seam Weld 1
90o
Longitudinal
Seam Weld 2
Root
Ref.2
Tubular Joints
offset (positive)
offset (positive)
BRACE
CHORD
CHORD
SIMPLE JOINT
Ref.2
Tubular Joints Disadvantage:
• No access to weld toe for future inspection
offset (negative)
CHORD
CHORD
OVERLAP JOINT
Ref.2
Tubular Joints
• Heavy wall
• Different material
2 inch
• Specifications
• Yield stress
Ref.2
Tubular Joints
2 inch
BOTTLE JOINT CAN
• Avoid overlaps on complicated joints
• Larger diameter
• Different material
• Specifications
• Yield stress
• May need internal stiffener rings
Ref.2
Tubular Joints
Ref.2
Tubular Joint
Ref.2
Referensi
1. Karl-Heinz Brensing, “Steel Tube and Pipe
Manufacturing Processes” Düsseldorf
2. Wisnu Mustapha “Steel and welding for
offshore structures”, Slide KU-KL, March
20, 2009
3. Zulfiadi Zulhan “Metallurgy of Iron and
Steelmaking“, MG-4113 Slide, 2009
4. Mardjono Siswosuwarno,”Logam dan
paduannya”, MT-1201 Note, 2005
5. Other references relevant..